Product ID:REFRIGERANT II
MSDS Date:06/01/1994
FSC:6830
NIIN:00-281-3036
MSDS Number: BYDZW

NATIONAL REFRIGERANTS INC

11401 ROOSEVELT BLVD
PHILADELPHIA, PA 19154
US

Emergency Phone: 215-834-0200

Info Phone: 215-834-0200

Preparer: T. NAPRAVA

Cage: 7Y146

NATIONAL REFRIGERANTS INC

PHILADELPHIA, PA 19154 US

Telephone: 215-834-0200

Cage: 7Y146

TRICHLOROFLUOROMETHANE (CFC-11) (SARA 313) (CERCLA)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORL RAT:>3725MG/KG;LC50 RAT 26200PPM/4HR
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR IS HEAVIER THAN AIR
AND CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR MAY CAUSE
LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF B REATH, & MAY LEAD TO
NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. SKIN:
IRRITATION.
Effects of Overexposure:SKIN:IRRITATION, DEFATTING. INHALATION:LIGHT
HEADEDNESS, SHORTNESS OF BREATH, CARDIAC IRREGULARITIES,
UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:PRE-EXISTING CNS AND CARDIOVASCULAR
DISEASES.

First Aid:INHALATION: REMOVE TO FRESH AIR, CALL PHYSICIAN. IF NOT
BREATHING, GIVE CPR, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS.
EYE: IN CASE O F CONTACT, IMMEDIATELY FLUSH EYES W/PLENTY OF WATER
FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. SKIN: FLUSH WITH PLENTY
OF WATER. INGESTION:DO NOT INDUCE VOMTING. CALL PHYSICIAN.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:ND
Extinguishing Media:USE MEDIA AS APPROPRIATE FOR SURROUNDING FIRES.
Fire Fighting Procedures:USE WATER SPRAY OR FOG TO COOL DRUMS. SELF-
CONTAINED BREATHING APPARATUS MAY BE REQUIRED IF DRUMS RUPTURE AND
CONTENTS ARE SPILLED UNDER FIRE CONDITIONS.
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS,
AND MAY EMIT TOXIC HYDROCHLORIC AND HYROFLUORIC ACIDS, AND POSSIBLE
CARBONYL HALIDES.

Spill Release Procedures:VENTILATE AREA. WEAR SCBA FOR LARGE SPILLS. DO
NOT FLUSH INTO SEWERS. DIKE SPILL. COLLECT ON ABSORBENT MATERIAL &
TRANSFER TO STEEL DRUMS FOR RECOVERY OR DISPOSAL. COMPLY W/FEDERAL,
STATE AND LOCAL RE GULATIONS OR REPORTING RELEASES.

Handling and Storage Precautions:STORE IN A CLEAN, DRY AREA. DO NOT
HEAT ABOVE 125 F.
Other Precautions:USE IN A WELL VENTILATED AREA.

Respiratory Protection:UNDER NORMAL CONDITIONS, NO RESPIRATORY
PROTECTION IS REQUIRED WHEN USING THIS PRODUCT. SELF-CONTAINED
BREATHING APPARATUS (SCBA) IS REQUIRED IF A LARGE SPILL OCCURS.
Ventilation:NORMAL VENT IS GENERALLY ADEQUATE. USE LOCAL EXHAUST WHEN
LARGE AMTS RELEASED. USE MECHANICAL VENT IN LOW PLACES.
Protective Gloves:BUTYL GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES
Work Hygienic Practices:USE IN A WELL VENTILATED AREA.
Supplemental Safety and Health

HCC:N1
Boiling Pt:B.P. Text:75.0F,23.9C
Vapor Pres:14.7PSI77F
Vapor Density:4.9 @77F
pH:NEUTRL
Evaporation Rate & Reference:>1 (CC14=1)
Solubility in Water:0.1% BY WT @ 77 F
Appearance and Odor:COLORLESS LIQUID; SLIGHT ETHERAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS - POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:HIGH TEMPS (OPEN FLAMES, GLOWING
SURFACES, ETC.) FORMING HYDROCHLORIC & HYDROFLUORIC ACIDS-POSSIBLE
CARBONYL HALIDES.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. SEND TO MFR FOR RECLAIM OR REMOVE TO A PERMITTED WASTE
DISPOSAL FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.